If rain water is pure or almost how is that any different than pure water you have produced going on ur plants?
True enough most times rainwater comes out at about 25ppm.
0.025ppm?

around Chepstow it rain water comes in at about 0.005 to 0.009ppm!
Over watering sounds the most likely reason, especially with ferns...
Try a few experiments, siphon off some pure water to look after a few indoor pot plants, make sure you have a couple of identical plants of course, water some with pure water and some with tap water, give it a few weeks and see what transpires...
Ian