A careful look at your idea shows that it really wouldn't work. In order to understand why not, we need to clear up a bit of thinking. It's common knowledge that the mains pressure affects the amount and purity of the product water. Well, that's not quite right. It's the
pressure difference between the inlet and the outlet.
Putting a second RO unit would cause a back pressure which would then reduce the pressure difference across the first unit and hence reduce its efficiency. This would increase the tds reading and increase the amount of waste water. The second unit would then have the same low pressure difference problem.
I hope the diagram makes it clear.

The two pressure differences are probably going to be the same as the pressure difference across a single unit. Having two units in series is going to hugely decrease the efficiency of each unit and lead to a huge increase in the waste water.
Sorry. It sounded like a good idea, but in practice, it simply won't work.