A regular rang me up today, can i get another red wine stain out? of course i can try i answered

what have you put on it this time i said? she said well, i remember you saying not to put vanish or "2099" on it so i blotted it and threw white wine on it?
Oh dear i said,

(she turned round and said ""should i have not of put the white wine on the red wine when i spilt it ?"
(i was caught a little off guard) My answer was "mmmmmm, No you shouldnt of, but i dont know the reason why, i can't remember what the chemical reaction is that happens when you do this."
i went on to explain about it setting the stain in, but my questin is, to you more experienced technicians is "what does happen when white wine is put onto red wine...............?
My other question is : Where on earth have people got this idea of white wine getting rid of red wine from?
And the red wine did come out as well, synthetic carpet!