Yes Dave, they are empty. They have been used in static commercial machinery, so have had very controlled usage.
The advantage to these vessels is their capacity, which allows for better movement of water through the Resin beads. Whether you choose to have them 'pre or post' is up to you. You do run the risk of errant beads damaging your pump if you use them 'pre' though.
If you find that the smaller units works for you then that's great. I would use the smaller 700ml as a final polish after your RO before filling your static tank and then you do not need one in your vehicle at all (we never do).
Even cheaper is to use the pressure vessel from your vehicle after your RO and then you do not have to buy anything new.