I've yet to hear a definitive answer myself, but the resin the water passes through is poisonous, but whether that also makes the water itself bad for you I'm not sure, it is just the resin itself that is bad.
some say that the purified water does things to your insides, but the moment it is inside your mouth it is no longer pure, and by the time it's in your stomach it is mixed up with all your digestive juices and anything else you've consumed!!
Just after the R/O has done its work its fine, and a good R/O will reduce the water to 0.001ppm (mine did when new)
Even though I do not know whether the resin will indeed make the water unsafe to drink or not, I still wouldn't do it!, just in case!!
I have done after the R/O though.
Ian