Hi Lee
You can do it that way but i would only recommend that in cases of emergency, the more your charging your leisure battery the more you drain you van battery, unless you do a lot of driving between jobs,
a lot of stop starts, and the charging from an inverter will almost certainly take its toll out of your van battery.
I would invest in the split charge relay if i were you, or you may find yourself with a flat battery, and even if your leisure battery is fully charged you wont be able to start your van with it.
Split charge relays work out so much cheaper than a new battery.
I personally have never wired a split charge relay and a few guy's seem to have a problem with the wiring, if any one wants to email me the instructions from a split charge relay, I will take a look and try to rewrite them into simple english for you.