Pic please I am interested not sure how it starts to flow without sucking
It's due to an unbalanced water pressure between the tanks.
Once one tank starts to lose water it has less pressure and so the water (through the pipe) will then move from the more full tank to the less full to create equal pressure (an equilibrium if you will

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Thats why you fill both with water first, and then get rid of the air in the piping, it then creates that siphon effect as the water will try to 'escape' to the lower pressure (less full) tank until both have equal amounts of water
You'd still want an half decent diameter piping though depending on how fast your ro produces
Its a very good idea to solve the problem!
