What r/o have you got?
you also need to take a sample of water from the r/o after the r/o has been processing water for about 5 minutes.
It easy to get an input tds reading as you just get that at the tap the r/o is connected to.
We had a 450gpd RoMan type r/o. It was one that had the third filter housing as a resin filter. The pipes were all connected together with John Guest couplings. Firstly, we unplugged the pipe from the pure outlets of the membranes to the resin filter. We then fitted another length of pipe into that fitting, diverting the water into a bucket. Once it had run for a while, we grabbed a sample from the running water and tested it with our tds meter.
We now have a 4040 and have made this problem easy by fitting an inline tds meter. Now with the press of a button we can read the r/o output before the di and then the output after di. The tds starts off very high when the r/o first starts but settles down to a 98 -99% efficiency within a couple of minutes.