If you plan on killing yourself then use 240v with water, just get some insurance first.
Secondly you will, unless you DI after the tank, need to get a special type of immersion as the regular ones will send the DI skyward, dont ask me why.
Anything running off 12v will need a battery the size of the van to generate enough power to raise the temp of the water.
If you go for gas heating check out the regs on carrying gas as they are quite prohibitive.