I,m Guessing from your name and the wording of your post that c/c cleaning is not your prime money earner!!
Have you cleaned any carpets before? if not I would suggest you call in a professional c/c , its not really much info to say a cream colour carpet, identification of the fibres and construction would be useful and the use of carpet shampoo alone would not in itself do the job, especially as from your post " i,m guessing here " you do not have an extraction machine.
Stain removal alone is a different ball game to carpet cleaning.
As for the head board , I am again having an educated guess here, it is likely to be a draylon or similar type fabric, I doubt it would be suede, again you require a professional for any chance of removal even then both items cannot be guaranteed to be completely free of the marks.
in my experience most make up does normally remove with out to much effort , ink can be a nightmare with one small spot literally covering a blotting towel .
Forgive me if i am reading your post wrong, if not heed my advise or you may be asking for more trouble than its worth.
geoff