morgan it does this, its down to salt diffusion when the merlin isn't producing water, its quite normal and as the shiner says just run off the first 5ltrs or so before running it through the di.
I have a little tap on mine before the 1st di which when open diverts the water into the drain, I close it after 5mins so the water then goes into di1 then di2
I use 2500ltrs a week on my own and a bag does me a year, even then I don't really need to change it but I only use water at 0ppm or maybe 1ppm.