I think that you might find that an auto electrician is the right person to ask about this.
As we only travel a short distance to work the leisure batteries in both vans need to be topped up every few days.
We started to have starting problem on the small van at the beginning of this winter and ended up replacing the van battery which has cured that problem. However, the leisure battery still needs to be regularily charged as it will go completely flat if its left.
You could have a mixture of many problems here. Maybe the van battery is a little dodgy and the leisure battery needs a good charging. If the alternator is spending all of its time trying to charge a faulty van battery then there is going to be less left to charge the leisure battery.
Or perhaps the alternator is not charging properly, or perhaps both van and leisure batteries need replacing. Hence my suggestion to get the problem checked out by someone who knows.
Hope this helps.
Spruce