Dear Forum,
Re: Leather Cleaner & pH Value
Dear Forum,
Re: pH Value and Leather Cleaners
As Pete wants to see discussion on leather that is more refreshing, I hope my contribution helps.
Some of you may have seen this posting in another forum already; it is about a “scary experience”!
This is my cut and paste from that forum:
Leather cleaning products that have a pH value beyond 3 and 5 either way, especially specialty spotters when used should be neutralized correspondently.
Products available for such safe neutralization is acidifier1.8™ and basifier8.5™.
A classic example of acid/alkali neutralization process equation may be express as Caustic Soda + Hydrochloric Acid = Salt (sodium chloride) + Water.
Why leather cleaning products pH values have to be between 3 and 5?
In leather, almost 30% of contents are chemistry the remaining are protein collagen fiber.
Some of the main chemistry present in leather is the Tannin Agents, Fatliquors, Dyestuffs, Preservatives, Stuffing Waxes and Oils beside others.
They are there not to be disturbed or destabilized otherwise gradually the leather denature and deteriorate.
pH tolerance on sensitive absorbent leather manifest as water spots even with clean water neutral pH 7.
High-end world famous leather furnishing manufacturers that produce “contemporary classics” fit for museum collection will cautions the use of water on their sensitive leathers.
A weak alkaline cleaner pH value of 8 to 10 will cause ring marks when dry.
A moderate alkaline pH value 11 to 12 will result in stickiness, sliminess or gumminess.
A strong alkaline pH value 13 to 14 will gelatinize and dissolve the leather.
Chrome tanning is process at pH value between 2 and 4.
Vegetable tanning is process at pH value between 3 and 5.
Fatliquoring is process at pH value between 4 and 6.
Dyeing with acid dyestuff is process at pH value between 3 and 4.
Most “Plastic” coating including heavy pigmented leather pH value reading at the surface seldom exceeds a pH value of 6.
The pH value reading of such leather surface by means of a “pH Glass Electrodes – HI 1414” is as follows:
Pigmented Kela pH 4.4
Pigmented Metallic pH 5.0
Pigmented High Gloss pH 5.9
Pigmented Fully Corrected pH 5.7
Pigmented Wiped Effect pH 5.8
Bicast pH 4.8
All these pH value from the intimate leather internal fibrilliary structure to the thick modern urethane coating that includes the leather simulated vinyl door panels of Mazda3 are all below a pH value of 6.
Alkalinity will cause streaks, which is why cleaning by foam is “sold” as the “in thing” which may not be “safe”.
The prime safety factor when comes to leather cleaning is using a “leather pH balanced product” and not just the “foam method” as some proponent has sold to unwary user.
The cleaning effectiveness should be a secondary consideration and it depends on cleaners’ type of surfactants concentration, the ability to penetrate, lubricate and suspense soil or having superior polarity to match severity of soiling.
The advantages of using “foam” when doing a vertical cleaning is that the foams stay longer therefore steaks may be eliminated when done fast.
Question is how you control the foam from breaking up for proper “dwell time”.
Dwell time is one big consideration for the chemical to work for us when using the “CHAT” principle of leather cleaning.
Solvency will affect the top coating, drawing out both the plasticizers from the flexible coating and the fatliquor from the leather structure.
Products with “Perchlorethylene” from petroleum distillate are a health issue too!
All this brings back to quote “I've seen far too many "Leather" products that should never be used on Leather”.
Tony may have seen more damages to leather using leather non-pH balanced solvency or alkalinity ingredients products than we may have been talking so far.
Roger Koh
IICRC#942 LCT MTC MSR
Leather Doctor® System
info@leatherdoctor.org