When I attended a Scotchgard training course, many, many years ago, they told us how to recover frost damaged product. Whether this information applies to other brands or indeed any current formulation, I don't know, but it won't hurt to try it.
Simply, heat the product in a bain-marie type of saucepan, stirring all the time.
Nothing ventured, nothing gained.
Don't use her best cookware and be H&S aware.
Safe and happy cleaning

The Ken